Researchers are using 3D printing to develop electrodes with the highest electric charge store per unit of surface area ever reported for a supercapacitor.

A research collaboration from the University of California Santa Cruz and the U.S. Department of Energy’s Lawrence Livermore National Laboratory have 3D printed a graphene aerogel that enabled them to develop a porous three-dimensional scaffold loaded with manganese oxide that yields better supercapacitor electrodes. The recently published their findings in Joule. Yat Li, a professor of chemistry and biochemistry at UC Santa Cruz, explained the breakthrough in an interview with R&D Magazine.

“So what we’re trying to address in this paper is really the loading of the materials and the amount of energy we can store,” Li said. “What we are trying to do is use a printing method to print where we can control the thickness and volume.

After what has seemed a bit of a lapse in the timeline of their development, graphene-enabled supercapacitors may be poised to make a significant advance. Researchers at the University of California, Santa Cruz, and Lawrence Livermore Laboratory (LLNL) have developed an electrode for supercapacitors made from a graphene-based aerogel. The new supercapacitor component has the highest areal capacitance (electric charge stored per unit of surface area) ever reported for a supercapacitor.

The 3D-printing technique they leveraged to make the graphene electrode may have finally addressed the trade-offs between the gravimetric (weight), areal (surface area), and volumetric (total volume) capacitance of supercapacitor electrodes that were previously thought to be unavoidable.

In previous uses of pure graphene aerogel electrodes with high surface area, volumetric capacitance always suffered. This issue has typically been exacerbated with 3D-printed graphene aerogel electrodes; volumetric capacitance was reduced even further because of the periodic large pores between the printed filaments.