Researchers at Osaka University synthesized twisted molecular wires just one molecule thick that can conduct electricity with less resistance compared with previous devices. This work may lead to carbon-based electronic devices that require fewer toxic materials or harsh processing methods.

Organic conductors, which are carbon-based materials that can conduct electricity, are an exciting new technology. Compared with conventional silicon electronics, organic conductors can be synthesized more easily, and can even be made into molecular wires. However, these structures suffer from reduced electrical conductivity, which prevents them from being used in consumer devices. Now, a team of researchers from The Institute of Scientific and Industrial Research and the Graduate School of Engineering Science at Osaka University has developed a new kind of molecular wire made from oligothiophene molecules with periodic twists that can carry electric current with less resistance.

Molecular wires are composed by several-nanometer-scale long molecules that have alternating single and double chemical bonds. Orbitals, which are states that electrons can occupy around an atom or molecule, can be localized or extended in space. In this case, the pi orbitals from individual atoms overlap to form large “islands” that electrons can hop between. Because electrons can hop most efficiently between levels that are close in energy, fluctuations in the polymer chain can create energy barriers. “The mobility of charges, and thus the overall conductivity of the molecular wire, can be improved if the charge mobility can be improved by suppressing such fluctuations,” first author Yutaka Ie says.